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ISO 15608 Material Groups

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ISO 15608 Material Groups

Material Group 51.3

Material Group 51.3 ISO 15608: Pure titanium with 0,25 < O2 ≤ 0,35 %

Features of Titanium pure Group 51.3 ISO 15608

Grade 3:
Moderate strength unalloyed Ti with excellent weldability, cold formability, and fabricability. Slightly stronger version of Gr. 2 Ti with similar corrosion resistance with good weldability and reasonable cold formability/ductility.
This grade material is mainly used in chemical industries and power plant cooling system components where the parts are subjected to very harsh environments.

Welding of Titanium pure Group 51.3 ISO 15608

Commercially pure titanium and most titanium alloys are readily welded by a number of welding processes being used today. The most common method of joining titanium is the gas Tungstenarc (GTAW) process and secondarily is the gas metal-arc (GMAW) process. The techniques for welding titanium resemble those employed with nickel alloys and stainless steels. To achieve sound welds with titanium, primary emphasis is placed on surface cleanliness and the correct use of inert gas shielding.
An essential requirement for successfully arc welding titanium is proper gas shielding. Care must be taken to ensure that inert atmosphere protection is maintained until the weld metal temperature cools below 426°C (800°F).

Typical materials in group 51.3

Name / GradeNumberStandardProductRemarks
Ti 33.7055DIN 17851
3
3
WPT 3
F-3
3
R50550
R50550
R50550
R50550
R50550
ASTM B-265
ASTM B-338
ASTM B-363
ASTM B-381
ASTM B-862
Plate & sheet
Smls. & welded tube
Fitting
Forgings
Welded pipe
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
Table: Typical materials

Material Group 51.4

Material Group 51.4 EN ISO 15608: Pure titanium with 0,35 < O2 ≤ 0,40 %

Typical materials in group 51.4

NameNumberStandardProductRemarks
C-2R52550ASTM B-367CastingASME BPVC
C-3R52550ASTM B-367CastingASME BPVC
Table: Typical materials

Material Group 52

Material Group 52 EN ISO 15608: Titanium alpha alloys a

a Alloys covered by group 52 are:
Ti-0,2Pd, Ti-2,5Cu, Ti-5Al-2,5Sn, Ti-8Al-1Mo-1V, Ti-6Al-2Sn-4Zr-2Mo and Ti-6Al-2Nb-1Ta-0,8Mo;

Features of Grade 12

Highly weldable and fabricable Ti alloy offering improved strength and pressure code design allowables, hot brine crevice corrosion, and reducing acid resistance compared to Ti Grades 1, 2, and 3. Approved for sour service use under the NACE MR0175/ISO 15156 Standard.

Typical materials in group 52

Name / GradeNumberStandardProductRemarks
11R52250ASTM B-265Plate & sheetASME BPVC
7
7
7
WPT 7
F-7
7
7
R52400
R52400
R52400
R52400
R52400
R52400
R52400
ASTM B-265
ASTM B-338
ASTM B-348
ASTM B-363
ASTM B-381
ASTM B-861
ASTM B-862
Plate & sheet
Smls. & welded tube
Bar
Smls. & welded … fittings
Forging
Smls. pipe
Welded pipe
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
7H
7H
7H
WPT 7H
F-7H
7H
7H
R52400
R52400
R52400
R52400
R52400
R52400
R52400
ASTM B-265
ASTM B-338
ASTM B-348
ASTM B-363
ASTM B-381
ASTM B-861
ASTM B-862
Plate & sheet
Smls. & welded tube
Bar
Smls. & welded … fittings
Forging
Smls. pipe
Welded pipe
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
12
12
WPT 12
F-12
12
12
R53400
R53400
R53400
R53400
R53400
R53400
ASTM B-265
ASTM B-338
ASTM B-363
ASTM B-381
ASTM B-861
ASTM B-862
Plate & sheet
Smls. & welded tube
Smls. & welded fittings
Forging
Smls. pipe
Welded pipe
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
Table: Typical materials

Material Group 53

Material Group 53 EN ISO 15608: Titanium alpha-beta alloys b;

b Alloys covered by group 53 are: Ti-3Al-2.5V, Ti-6Al-4V, Ti-6Al-6V-2Sn, Ti-7Al-4Mo;

Features of Titanium alpha-beta alloys

Grade 5:
Ti-6Al-4V (Titanium Grade 5) is the most widely used of all the alpha-beta titanium alloys accounting for more than 50% of total titanium usuage. It is typically used in the annealed condition, at service temperatures through 400°C (750°F).
A major industrial application for this titanium grade is in heat transfer applications such titanium condenser, shell and tube heat exchangers and plate and frame heat exchangers are used extensively in power plants, refineries, chemical plants and offshore platforms. Grade 5 is readily weldable using GTAW or TIG processes if adequate shielding is provided using pure inert gas (Argon or Helium). Use of a trailing shield is recommended. Titanium must be free of oil, grease or other contamination before welding.

Grade 9:
Medium strength, non-ageable Ti alloy (Ti-3Al-2.5V) offering highest strength and design allowables under the pressure vessel code, with good weldability and cold fabricability for mildly reducing to mildly oxidizing media. It offers 20 to 50% higher tensile strength than the commercially pure titanium at room and elevated temperatures. It is much more amenable to cold working than Ti 6AI/4V alloy and can be cold worked 75 to 85% to result in moderately high strength and good ductility. 

Grade 28:
Ru-enhanced version of (Ti-3Al-2.5VRu) with equivalent physical and mechanical properties and fabricability, offering elevated resistance to dilute reducing acids and crevice corrosion in hot halide (brine) media. Approved for sour service use under the NACE MR-01-75 Standard.

Grade 38:
Is an alpha-beta titanium alloy that uses iron and vanadium as beta stabilizers as well as aluminum as an alpha stabilizer. The lower aluminum and vanadium contents and higher oxygen and iron contents give ATI 425® alloy a unique combination of ductility and tensile strength. The excellent ductility permits forming at room temperature. Is easily welded in the annealed condition using methods typically applied to titanium, such as TIG, MIG.

Typical materials in group 53

Name / GradeNumberStandardProductRemarks
Ti-6Al-4V
(Grade 5)
3.7165DIN 17851
Grade 93.7195DIN 17851
9
9
9
WPT 9
F-9
9
9
R56320
R56320
R56320
R56320
R56320
R56320
R56320
ASTM B-265
ASTM B-338
ASTM B-348
ASTM B-363
ASTM B-381
ASTM B-861
ASTM B-862
Plate & sheet
Smls. & welded tube
Bar
Smls. & welded fitting
Forging
Smls. pipe
Welded pipe
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
28
28
28
WPT 28
F-28
28
28
R56620
R56620
R56620
R56620
R56620
R56620
R56620
ASTM B-265
ASTM B-338
ASTM B-348
ASTM B-363
ASTM B-381
ASTM B-861
ASTM B-862
Plate & sheet
Smls. & welded tube
Bar
Smls. & welded fitting
Forging
Smls. pipe
Welded pipe
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
38
38
38
WPT 38
F-38
38
38
R54250
R54250
R54250
R54250
R54250
R54250
R54250
ASTM B-265
ASTM B-338
ASTM B-348
ASTM B-363
ASTM B-381
ASTM B-861
ASTM B-862
Plate & sheet
Smls. & welded tube
Bar
Smls. & welded fitting
Forging
Smls. pipe
Welded pipe
ASME BPVC & Code Case 2532-2
ASME BPVC & Code Case 2532-2
ASME BPVC & Code Case 2532-2
ASME BPVC & Code Case 2532-2
ASME BPVC & Code Case 2532-2
ASME BPVC & Code Case 2532-2
ASME BPVC & Code Case 2532-2
Table: Typical materials

Material Group 54

Material Group 54 EN ISO 15608: Titanium near beta and beta alloys c

c Alloys covered by group 54 are:
Ti-10V-2Fe-3Al, Ti-13V-11Cr-3Al, Ti-11.5Mo-6Zr-4.5Sn, Ti-3Al-8V-6Cr-4Zr-4Mo;

Ti-3Al-8V-6Cr-4Zr-4Mo

This grade is a metastable beta titanium alloy known of its exceptional ductility in the solution treated (annealed) condition, and for its heigh strength and ductility in the solution treated and aged condition. Improved tensile properties can be achieved , while maintaining good ductility and low modus of elasticity. Fatigue strength is also good in the solution treated and aged condition.
This grade find applications in high strength commercial applications, structural parts , gas and petroleum down-hole and piping systems and fasteners and can be used for extended periods in elevated temperature environment below 349°C.

Typical materials in group 54

Name / GradeNumberStandardProductRemarks
Grade 193.7145DIN 17851
Ti-3Al-8V-6Cr-4Zr-4Mo
(Grade 19)
R58640
R58640
R58640
R58640
R58640
R58640
R58640
ASTM B-265
ASTM B-338
ASTM B-348
ASTM B-363
ASTM B-381
ASTM B-861
ASTM B-862
Plate
Seamless and welded tube
Bar
Seamless and welded fittings
Forgings
Seamless pipe
Welded pipe
ATI 38-644™
Table: Typical materials

Material Group 61

Material Group 61 ISO/TR 1568: Pure zirconium

Features of pure Zirconium

Zirconium, a reactive metal, ha s high affinity for oxygen that results in the formation of a protective oxide layer in air at room temperature. This protective oxide gives this alloy their superior corrosion resistance and this oxide layer can be enhanced through a heat process.

This material exhibit good ductility even at cryogenic temperatures and good strength comparable with other common engineering alloys.

Applications of pure Zirconium

One of the major applications of Zirconium is as a corrosion-resistant material of construction for the chemical processing industry. Zirconium exhibits excellent resistance to corrosive attack in most organic and inorganic acids, salt solutions, strong alkalis, and some molten salts. Some of the more important areas in the chemical processing industry where Zirconium is being used include Reboilers, Evaporators, Tanks, Packings, Trays, Reactor Vessels, Pumps, Valves and Piping.

This material is ideal for heat exchanger applications. The linear coefficient of thermal expansion of this material is nearly one-third of the value for stainless steel giving this material superior dimensional stability at elevated temperatures.

Zirconium is weldable and the stress relief heat treatment after welding (PWHT) should be performed within 14 days after welding.

Typical materials in group 61

Name / GradeNumberStandardProductRemarks
R60702
R60702
R60702
R60702
702C
R60702
R60702
R60702
R60702
R60702
ASTM B-493
ASTM B-523
ASTM B-653
ASTM B-658
ASTM B-752
Forging
Smls. & welded tube
Smls. & welded fittings
Smls. & welded pipe
Casting
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
Zircaloy-2R60802ASTM B-351
ASTM B-352
ASTM B-353
Bar
Plate
Seamless and welded tube
Zircaloy-4R60804ASTM B-351
ASTM B-352
ASTM B-353
Bar
Plate
Seamless and welded tube
Table: Typical materials

Material Group 62

Material Group 62 EN ISO 15608: Zirconium with 2,5 % Nb

Features of Zirconium with 2,5 % Nb

This material is alloyed with niobium to increase its strength and improve its formability. Zirconium, a reactive metal, ha s high affinity for oxygen that results in the formation of a protective oxide layer in air at room temperature. This protective oxide gives this alloy their superior corrosion resistance and this oxide layer can be enhanced through a heat process.

This alloy exhibit good ductility even at cryogenic temperatures and good strength comparable with other common engineering alloys.

This alloy is ideal for heat exchanger applications. The linear coefficient of thermal expansion of this material is nearly one-third of the value for stainless steel giving this material superior dimensional stability at elevated temperatures.

Zirconium is weldable and the stress relief heat treatment after welding (PWHT) should be performed within 14 days after welding.

Typical materials in group 62

Name / GradNumberStandardProductRemarks
R60705
R60705
R60705
R60705
R60705
705C
R60705
R60705
R60705
R60705
R60705
R60705
ASTM B-493
ASTM B-523
ASTM B-550
ASTM B-551
ASTM B-658
ASTM B-752
Forging
Smls. & welded tube
Bar
Plate & sheet
Smls. & welded pipe
Casting
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
ASME BPVC
Zr-2.5NbR60904ASTM B-353Smls. & welded tube
Table: Typical materials

Material Group 71

Material Group 71 ISO 15608: Grey cast irons with specified tensile strength or Brinell hardness

Typical materials in group 71

NameNumberStandardsRemarks
EN-GJL-150EN-JL1020EN 1561
EN-GJL-200 EN-JL1030EN 1561
EN 12516-4
EN 12953: Valve DN ≤200, PS≤13 bar, TS≤220°C
EN-GJL-250EN-JL1040EN 1561
EN 12516-4
EN 12953: Valve DN ≤200, PS≤13 bar, TS≤220°C
EN-GJL-300EN-JL1050EN 1561
EN-GJL-350EN-JL1060EN 1561
EN-GJL-HB155EN-JL2010EN 1561
EN-GJL-HB175EN-JL2020EN 1561
EN-GJL-HB195EN-JL2030EN 1561
EN-GJL-HB215EN-JL2040EN 1561
EN-GJL-HB235EN-JL2050EN 1561
EN-GJL-HB255EN-JL2060EN 1561
Table: Typical materials

Material Group 72.1

Material Group 72.1 EN ISO 15608: Spheroidal graphite cast iron, ferrite type, with specified tensile strength 0,2 % proof test, elongation and specified impact resistance values

Typical materials in group 72.1

NameNumberStandardsRemarks
EN-GJS-350-22EN-JS1010EN 1563EN 13445-6
EN-GJS-400-18EN-JS1020EN 1563EN 13445-6
EN-GJS-400-15EN-JS1030EN 1563
EN 12516-4
EN-GJS-4S0-10EN-JS1040EN 1563
EN-GJS-500-7EN-JS1050EN 1563
EN 12516-4
EN-GJS-600-3EN-JS1060EN 1563
EN 12516-4
EN-GJS-700-2EN-JS1070EN 1563
EN-GJS-800-2EN-JS1080EN 1563
EN-GJS-900-2EN-JS1090EN 1563
EN-GJS-900-2UEN-JS1122EN 1563
EN-GJS-HB130EN-JS2010EN 1563
EN-GJS-HB150EN-JS2020EN 1563
EN-GJS-HB155EN-JS2030EN 1563
EN-GJS-HB185EN-JS2040EN 1563
EN-GJS-HB200ENJ-S2050EN 1563
EN-GJS-HB230EN-JS2060EN 1563
EN-GJS-HB260EN-JS2070EN 1563
EN-GJS-HB300EN-JS2080EN 1563
EN-GJS-HB330EN-JS2090EN 1563
Table: Typical materials

ISO 15608 groups materials according to their similar properties such as chemical composition, weldability and mechanical properties. However, it can also be used for other applications such as NDE, forming or heat treatments.

Material assigned to a group in ISO/TR 20172 (European Materials), ISO/TR 20173 (American Materials) and ISO/TR 20174 (Japanese Materials) should considered to those groups.

ISO 15608 material groups reduces the number of welding procedure qualifications (WPQR) e.g. ISO 15614-1. One WPQR is required for a single material group, whereby this material group can contain several specific materials (see tables below). For example, A WPQR with a material from subgroup 1.2 includes all materials from the subgroup 1.1

ISO 15608 is included in many codes and standards so that this simplification of welding qualifications can be used there e.g. EN 13445-2, EN 13480-2, AD 2000, PD 5500, EN 1092-2, ISO 9606.

ASME BPVC Section X has a similar group classification (P-number), but cannot be adopted 1:1. The American system similarly classifies materials into groups, however ASME BPVC Sect. IX in QW422 explicitly classifies grades of materials to groups and not on the chemical composition and mechanical properties such as is the case with ISO 15608.

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